- A Concise Asymmetric Route to Chiral alpha-Aminoxy Acids
[作者:CHANG XIAOWEI; ZHANG DANWEI; CHEN FEI; DONG ZEMIN; YANG DAN,期刊:SYNLETT, 页码:3159-3162 , 文章类型: Article,,卷期:2009年-19]
- An efficient three-step method has been developed for enantioselective synthesis of chiral alpha-aminoxy acids from aldehydes. In this method, chiral propargylic alcohols are obtained by asymmetric addition of terminal a...
- Ring Expansion of 2-Alkenyl Azetidines into Unsaturated Azocanes
[作者:DROUILLAT BRUNO; COUTY FRANCOIS; RAZAFIMAHALEO VANESSA,期刊:SYNLETT, 页码:3182-3186 , 文章类型: Article,,卷期:2009年-19]
- Enantiomerically pure 2-alkenyl azetidines undergo a ring-expansion into N-alkyl-1,2,3,6-azocines upon reaction with activated alkynes (ethyl propiolate or ethynyl p-tolyl sulfone). The scope of this ring enlargement, wh...
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