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Silver-Catalyzed Intermolecular Hydroamination of Alkenes and 1,3-Dienes

  作者 GINER XAVIER; NAJERA CARMEN  
  选自 期刊  SYNLETT;  卷期  2009年-19;  页码  3211-3213  
  关联知识点  
 

[摘要]Silver triflate is used as efficient catalyst for the intermolecular addition of 4-toluenesulfonamide to alkenes under thermal or microwave heating. The hydroamination of 1,3-dienes can be performed at 85 degrees C with low catalyst loading (0.1-5 mol%) or at room temperature Using 1 mol% of AgOTf, the use of HOTf affording similar results.

 
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