- Enzymatic Formation of Unnatural Novel Chalcone, Stilbene, and Benzophenone Scaffolds by Plant Type III Polyketide Synthase.
[作者:Shi, She-Po;Wanibuchi, Kiyofumi;Morita, Hiroyuki;Endo, Kohei;Noguchi, Hiroshi;Abe, Ikuro;,期刊:Organic Letters, 页码:551-554 , 文章类型: 研究论文,,卷期:2009年11-3]
- plant-specific type III polyketide synthase (PKS). Remarkably, the C21 chalcone-forming activity was dramatically increased in a structure-guided OKS N222G mutant that produces a C20 decaketide SEK15 from 10 mols. of ma...
- Facile Synthesis of 2-O-Iodoacetyl Protected Glycosyl Iodides: Useful Precursors of 1 ?2-Linked 1,2-trans-Glycosides.
[作者:Ko, Yoon-Joo;Shim, Seung-Bo;Shin, Jung-Hyu;,期刊:Organic Letters, 页码:609-612 , 文章类型: 研究论文,,卷期:2009年11-3]
- The prepn. and utilization of novel iodide glycosyl donors, 2-O-iodoacetyl-glycopyranosyl iodides, is described. The mechanism for the reaction of iodine with carbohydrate cyclic ketene acetal was investigated through l...
- Total synthesis of (?-hasubanonine.
[作者:Jones, Spencer B.;He, Liwen;Castle, Steven L.;,期刊:Organic Letters, 页码:785-785 , 文章类型: 研究论文,,卷期:2009年11-3]
- On page 3759, in Scheme 4, the product of the reaction was detd. to be rearranged isomer 17 as opposed to hasubanonine 1. Compd. 17 should be removed from Scheme 3 and Scheme 5 should be retracted along with the paragra...
- PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling.
[作者:Lipshutz, Bruce H.;Ghorai, Subir;,期刊:Organic Letters, 页码:705-708 , 文章类型: 研究论文,,卷期:2009年11-3]
- Amphiphilic ruthenium carbenes I [R = Me(OCH2CH2)n; R1 = all-(E)-Me2C:CHCH2(CH2CMe:CHCH2)9; R2 = Me, R1; R3 = R1, Me; Cy = cyclohexyl], derived from dihydro coenzyme Q10, is prepd.; the regioisomers of I function as recy...
- Total Synthesis of Pseudodehydrothyrsiferol.
[作者:Hioki, Hideaki;Motosue, Masatoshi;Mizutani, Yasuhiko;Noda, Akira;Shimoda, Tomoaki;Kubo, Miwa;Harada, Kenichi;Fukuyama, Yoshiyasu;Kodama, Mitsuaki;,期刊:Organic Letters, 页码:579-582 , 文章类型: 研究论文,,卷期:2009年11-3]
- An enantioselective total synthesis of pseudodehydrothyrsiferol (I) has been accomplished. The synthetic sequence highlights formation of the highly strained tetrahydropyran C-ring by a Mitsunobu-type SN2 reaction with ...
- Si-Based Benzylic 1,4-Rearrangement/Cyclization Reaction.
[作者:Trost, Barry M.;Bertogg, Andreas;,期刊:Organic Letters, 页码:511-513 , 文章类型: 研究论文,,卷期:2009年11-3]
- The trans-selective hydrosilylation of ynones yields b-silylated enones that undergo a benzylic 1,4-rearrangement/cyclization reaction in the presence of base, yielding 2,5-dihydro-1,2-oxasiloles, e.g. 95 % 5-ethyl-3-(fu...
- Regiocontrolled Cobalt-Catalyzed Diels-Alder Reactions of Silicon-Functionalized, Terminal, and Internal Alkynes.
[作者:Hilt, Gerhard;Janikowski, Judith;,期刊:Organic Letters, 页码:773-776 , 文章类型: 研究论文,,卷期:2009年11-3]
- The efficient control of the regiochem. of the Diels-Alder adducts (isolated as substituted benzenes after oxidn. by DDQ), which are formed in excellent yields from 2-methyl-1,3-butadiene and alkynylsilanes, can be reali...
- Synthesis of 3-Hydroxypyridines Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis.
[作者:Yoshida, Kazuhiro;Kawagoe, Fumihiro;Hayashi, Kazushi;Horiuchi, Shingo;Imamoto, Tsuneo;Yanagisawa, Akira;,期刊:Organic Letters, 页码:515-518 , 文章类型: 研究论文,,卷期:2009年11-3]
- New synthetic routes to substituted 3-hydroxypyridines are presented. Ring-closing olefin metathesis (RCM)/elimination and RCM/oxidn./deprotection of nitrogen-contg. dienes are the key processes of the routes. An applic...
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