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A Guanidinium Ion-Based Anion- and Solvent Polarity-Controllable Molecular Switch.

  作者 Lin, Tzu-Chiun;Lai, Chien-Chen;Chiu, Sheng-Hsien;  
  选自 期刊  Organic Letters;  卷期  2009年11-3;  页码  613-616  
  关联知识点  
 

[摘要]The macrocycle bis-p-xylyl[26]crown-6 (BPX26C6) is capable of complexing guanidinium ions in a [2]pseudorotaxane-like manner in soln. A corresponding mol. switch can be operated through changes in solvent polarity or the addn. and removal of halogen and acetate anions.

 
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