- Efficient Synthesis of Fluoren-9-ones by the Palladium-Catalyzed Annulation of Arynes by 2-Haloarenecarboxaldehydes.
[作者:Waldo, Jesse P.;Zhang, Xiaoxia;Shi, Feng;Larock, Richard C.;,期刊:Journal of Organic Chemistry, 页码:6679-6685 , 文章类型: 研究论文,,卷期:2008年73-17]
- Fluoren-9-ones and derivs. are readily prepd. in good yields by the annulation of in situ generated arynes by 2-haloarenecarboxaldehydes in the presence of a palladium catalyst. E.g., in presence of CsF, Pd(dba)2, and p...
- A Practical and Efficient Route for the Highly Enantioselective Synthesis of Mexiletine Analogues and Novel b-Thiophenoxy and Pyridyl Ethers.
[作者:Huang, Kun;Ortiz-Marciales, Margarita;Stepanenko, Viatcheslav;De Jesus, Melvin;Correa, Wildeliz;,期刊:Journal of Organic Chemistry, 页码:6928-6931 , 文章类型: 研究论文,,卷期:2008年73-17]
- A practical and efficient procedure for the enantioselective synthesis of mexiletine analogs, e.g. I, with use of 10% of spiroborate ester II as chirality transfer agent is presented. A variety of mexiletine analogs wer...
- A Xerogel-Sequestered Selenoxide Catalyst for Brominations with Hydrogen Peroxide and Sodium Bromide in an Aqueous Environment.
[作者:Bennett, Stephanie M.;Tang, Ying;McMaster, Danielle;Bright, Frank V.;Detty, Michael R.;,期刊:Journal of Organic Chemistry, 页码:6849-6852 , 文章类型: 研究论文,,卷期:2008年73-17]
- 4-(Hydroxymethyl)phenyl benzyl selenoxide sequestered in a 3-aminopropyltriethoxysilane/tetraethoxysilane catalyzes the bromination of org. substrates (4-pentenoic acid, 3,5-dihydroxybenzoic acid, 1,3,5-trimethoxybenzene...
- A Protecting Group Free Synthesis of (?-Neostenine via the [5 + 2] Photocycloaddition of Maleimides.
[作者:Lainchbury, Michael D.;Medley, Marcus I.;Taylor, Piers M.;Hirst, Paul;Dohle, Wolfgang;Booker-Milburn, Kevin I.;,期刊:Journal of Organic Chemistry, 页码:6497-6505 , 文章类型: 研究论文,,卷期:2008年73-17]
- A concise, linear synthesis of the Stemona alkaloid (?-neostenine (I) is reported. Key features include an organocopper-mediated bislactone C2-desymmetrization for the stereoselective construction of the cyclohexane-lac...
- Mild and Highly Efficient Method for the Synthesis of 2-Arylbenzimidazoles and 2-Arylbenzothiazoles.
[作者:Bahrami, Kiumars;Khodaei, M. Mehdi;Naali, Fardin;,期刊:Journal of Organic Chemistry, 页码:6835-6837 , 文章类型: 研究论文,,卷期:2008年73-17]
- A new, convenient method for the synthesis of C-2 substituted benzimidazoles and benzothiazoles was described. Thus, heterocyclization of 1,2-phenylenediamine with PhCHO in MeCN contg. aq. H2O2 and ceric ammonium nitrat...
- Sulfur-Directed Enantioselective Synthesis of Functionalized Dihydropyrans.
[作者:Fernandez de la Pradilla, Roberto;Tortosa, Mariola;Lwoff, Nadia;del Aguila, Miguel A.;Viso, Alma;,期刊:Journal of Organic Chemistry, 页码:6716-6727 , 文章类型: 研究论文,,卷期:2008年73-17]
- The highly selective base-promoted cyclization of enantiopure sulfinyl dienols affords allylic sulfinyl dihydropyrans. The scope of this methodol., including the prepn. of seven-membered rings, was studied in depth. Th...
- An Improved Asymmetric Synthesis of Malyngamide U and Its 2'-Epimer.
[作者:Feng, Jian-Peng;Shi, Zi-Fa;Li, Yang;Zhang, Jun-Tao;Qi, Xian-Liang;Chen, Jie;Cao, Xiao-Ping;,期刊:Journal of Organic Chemistry, 页码:6873-6876 , 文章类型: 研究论文,,卷期:2008年73-17]
- An accelerated and improved asym. synthesis of malyngamide U (I) and its 2'-epimer was accomplished from readily available n-hexanal, ethanolamine and (R)-(-)-carvone. The key steps involved a Johnson-Claisen rearrangem...
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