- Transition metal-free direct C-H bond thiolation of 1,3,4-oxadiazoles and related heteroarenes
[作者:ZOU LIANGHUA; REBALL JENS; MOTTWEILER JAKOB; BOLM CARSTEN,期刊:Chemical Communications, 页码:11307-11309 , 文章类型: Article,,卷期:2012年48-92]
- A convenient transition metal-free procedure for the direct thiolation of 1,3,4-oxadiazole C-H bonds using diaryl disulfides has been developed. Other substrates including indole, benzothiazole, N-phenylbenzimidazole, an...
- A cationic gold complex cleaves BArF24
[作者:WEBER SIMONE G; ZAHNER DAVID; ROMINGER FRANK; STRAUB BERND F,期刊:Chemical Communications, 页码:11325-11327 , 文章类型: Article,,卷期:2012年48-92]
- A sterically shielded cationic NHC gold complex IPr**Au-BArF24 without solvent coordination has been prepared in situ in CH2Cl2-. The monovalent transition metal electrophile, a "soft proton'', heterolytically activates ...
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