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Transition metal-free direct C-H bond thiolation of 1,3,4-oxadiazoles and related heteroarenes

  作者 ZOU LIANGHUA; REBALL JENS; MOTTWEILER JAKOB; BOLM CARSTEN  
  选自 期刊  Chemical Communications;  卷期  2012年48-92;  页码  11307-11309  
  关联知识点  
 

[摘要]A convenient transition metal-free procedure for the direct thiolation of 1,3,4-oxadiazole C-H bonds using diaryl disulfides has been developed. Other substrates including indole, benzothiazole, N-phenylbenzimidazole, and caffeine were also thiolated in this manner, providing the corresponding products in good to excellent yields.

 
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