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Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)(3)Si)(3)P and B(C6F4H)(3) with H-2 and CO2

  作者 TAKEUCHI KATSUHIKO; STEPHAN DOUGLAS W  
  选自 期刊  Chemical Communications;  卷期  2012年48-92;  页码  11304-11306  
  关联知识点  
 

[摘要]The 1 : 1 mixture of tris(trimethylsilyl)phosphine and tris(2,3,5,6-tetrafluorophenyl)borane behaves as frustrated Lewis pair (FLP) and shows H-2 and sequential two-step double CO2 activation with subsequent Me3Si group transfer.

 
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