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[摘要]:Reactions of the [1,2-(NH)(2)C6H4](2-) dianion (LH22-) with Cp2MII (M = V, Mn) lead to complete or partial oxidation of the metals (M), giving the V-III compound [(eta(5)-Cp)(LH2)(2)-VV( LH2)](-)[Li(THF)(4)](+) (1) and (Mn4Mn2III)-Mn-II oxo cage [Mn-6(LH2)(6)(mu(6)-O)(THF)(4)] (2). |
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