- Evaluation of electron population terms for WrSe-3V4p, WrS-3V3p, and WrO-3V2p: How do HOMO and LUMO shrink or expand depending on nuclear charges?.
[作者:Nakanishi, Waro;Hayashi, Satoko;Narahara, Kenji;Yamaki, Daisuke;Hada, Masahiko;,期刊:Chemistry-A European Journal, 页码:7278-7284 , 文章类型: 研究论文,,卷期:2008年14-24]
- Electron population terms WrN-3V are evaluated for N = Se, S, and O. Calcns. are performed on HOMO and LUMO constructed by pure at. 4p(Se), 3p(S), and 2p(O) orbitals, employing the 6-311+G(3d) and/or levels. Se4+, Se2+,...
- Coordination chemistry of conformation-flexible 1,2,3,4,5,6- cyclohexanehexacarboxylate: trapping various conformations in metal-organic frameworks.
[作者:Wang, Jing;Lin, Zhuo-Jia;Ou, Yong-Cong;Shen, Yong;Herchel, Radovan;Tong, Ming-Liang;,期刊:Chemistry-A European Journal, 页码:7218-7235 , 文章类型: 研究论文,,卷期:2008年14-24]
- 77 To study the conformations (configurations) of 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H6L), eleven new coordination polymers were isolated from hydrothermal reactions of different metal salts with all cis 1e,2a,3...
- Na8[Cr4B12P8O44(OH)4][P2O7].nH2O: a 3D borophosphate framework with spherical cages.
[作者:Yang, Tao;Sun, Junliang;Li, Guobao;Eriksson, Lars;Zou, Xiaodong;Liao, Fuhui;Lin, Jianhua;,期刊:Chemistry-A European Journal, 页码:7212-7217 , 文章类型: 研究论文,,卷期:2008年14-24]
- A Cr borophosphate-phosphate (Na8[Cr4B12P8O44(OH)4][P2O7].nH2O, 1), which has an unusual 3-dimensional framework structure, was synthesized under hydrothermal conditions. The framework consists of spherical cages compos...
- Ester hydrolysis by a cyclodextrin dimer catalyst with a metallophenanthroline linking group.
[作者:Zhou, Ying-Hua;Zhao, Meng;Mao, Zong-Wan;Ji, Liang-Nian;,期刊:Chemistry-A European Journal, 页码:7193-7201 , 文章类型: 研究论文,,卷期:2008年14-24]
- A novel b-cyclodextrin dimer, 1,10-phenanthroline-2,9-dimethyl-bridged-bis(6-monoammonio-b-cyclo dextrin) (phenBisCD, L), was synthesized. Its Zn complex (ZnL) was prepd., characterized, and applied as a new catalyst fo...
- Helicate extension as a route to molecular wires.
[作者:Schultz, David;Biaso, Frederic;Shahi, Abdul Rehaman Moughal;Geoffroy, Michel;Rissanen, Kari;Gagliardi, Laura;Cramer, Christopher J.;Nitschke, Jonathan R.;,期刊:Chemistry-A European Journal, 页码:7180-7185 , 文章类型: 研究论文,,卷期:2008年14-24]
- We describe the prepn. of a helicate contg. four closely spaced, linearly arrayed copper(I) ions. This product may be prepd. either directly by mixing copper(I) with a set of precursor amine and aldehyde helicate upon a...
- Metal-directed dynamic formation of tertiary structure in foldamer assemblies: orienting helices at an angle.
[作者:Delsuc, Nicolas;Hutin, Marie;Campbell, Victoria E.;Kauffmann, Brice;Nitschke, Jonathan R.;Huc, Ivan;,期刊:Chemistry-A European Journal, 页码:7140-7143 , 文章类型: 研究论文,,卷期:2008年14-24]
- Metal-directed assembly dictates the perpendicular or parallel orientation of helically folded arom. oligoamide modules and mediates the communication of their relative handedness. The synthesis and crystal structure of...
- Time-evolving self-organization and autonomous structural adaptation of cobalt(II) - organic framework materials with scu and pts nets.
[作者:Wu, Jing-Yun;Yang, Shang-Li;Luo, Tzuoo-Tsair;Liu, Yen-Hsiang;Cheng, Yi-Wei;Chen, Yen-Fu;Wen, Yuh-Sheng;Lin, Lee-Gin;Lu, Kuang-Lieh;,期刊:Chemistry-A European Journal, 页码:7136-7139 , 文章类型: 研究论文,,卷期:2008年14-24]
- The spontaneous, dynamic adjustment of equil. condition (KI/CoII ratio) is a key factor in switching the assembly direction of CoII and K4btec (btec = benzene-1,2,4,5-tetracarboxylate). {K2[Co3(btec)2(H2O)4]?H2O}n (1) wi...
- Partial substitution of hydroxyl by azide: an unprecedented 2D azido-copper-hydroxyl compound with a [Cu24] macrocycle in the presence of [Cu(H2O)6]2+.
[作者:Zeng, Yong-Fei;Hu, Xin;Zhao, Jiong-Peng;Hu, Bo-Wen;Sanudo, E. Carolina;Liu, Fu-Chen;Bu, Xian-He;,期刊:Chemistry-A European Journal, 页码:7127-7130 , 文章类型: 研究论文,,卷期:2008年14-24]
- The synthesis of an unprecedented 2-dimensional inorg. azido-Cu-hydroxyl compd. [Cu(H2O)6][{Cu2(N3)4/3(OH)(pta)}6] (H2pta = phthalic acid) was accomplished by partially substituting hydroxyl by azide. In this compd., [C...
- Synthesis and relaxometric studies of a dendrimer-based pH-responsive MRI contrast agent.
[作者:Ali, M. Meser;Woods, Mark;Caravan, Peter;Opina, Ana C. L.;Spiller, Marga;Fettinger, James C.;Sherry, A. Dean;,期刊:Chemistry-A European Journal, 页码:7250-7258 , 文章类型: 研究论文,,卷期:2008年14-24]
- The design of effective pH responsive MRI contrast agents is a key goal in the development of new diagnostic methods for conditions such as kidney disease and cancer. A key factor detg. the effectiveness of an agent is ...
- Recognition of ionic guests by ionic b-cyclodextrin derivatives.
[作者:Wenz, Gerhard;Strassnig, Christian;Thiele, Carolin;Engelke, Annegret;Morgenstern, Bernd;Hegetschweiler, Kaspar;,期刊:Chemistry-A European Journal, 页码:7202-7211 , 文章类型: 研究论文,,卷期:2008年14-24]
- of tert-butylbenzene complexed in b-cyclodextrin and its ionic 6-mono and 6-hepta derivs. were systematically investigated by isothermal titrn. calorimetry (ITC). All inclusion compds. showed 1:1 stoichiometry with bind...
- 1,2-Disilacyclobut-2-enes: donor-free four-membered cyclic silenes from reaction of disilenides with vinylbromides.
[作者:Bejan, Iulia;Inoue, Shigeyoshi;Ichinohe, Masaaki;Sekiguchi, Akira;Scheschkewitz, David;,期刊:Chemistry-A European Journal, 页码:7119-7122 , 文章类型: 研究论文,,卷期:2008年14-24]
- Cyclization of unstable intermediate vinyldisilene, generated by coupling of disilenyllithium R2Si:SiRLi (3a,b) and vinyl bromides BrCR1:CH2 gave 1,1,2-R3-3-R1-1,4-dihydro-1,2-disiletes (5a-e; a R = 2,4,6-iPr3C6H2, R1 = ...
- Dependence of enantioselectivity on the ligand/metal ratio in the asymmetric Michael addition of indole to benzylidene malonates: electronic influence of substrates.
[作者:Schaetz, Alexander;Rasappan, Ramesh;Hager, Markus;Gissibl, Anja;Reiser, Oliver;,期刊:Chemistry-A European Journal, 页码:7259-7265 , 文章类型: 研究论文,,卷期:2008年14-24]
- Simple bis(oxazoline) ligands, esp. azabis(oxazolines), can promote the copper(II)-catalyzed Michael addn. of indoles to benzylidene malonates with up to >99% ee (ee = enantiomeric excess), provided that the ligand/metal...
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