【文章名】Partial substitution of hydroxyl by azide: an unprecedented 2D azido-copper-hydroxyl compound with a [Cu24] macrocycle in the presence of [Cu(H2O)6]2+.
Partial substitution of hydroxyl by azide: an unprecedented 2D azido-copper-hydroxyl compound with a [Cu24] macrocycle in the presence of [Cu(H2O)6]2+.
作者
Zeng, Yong-Fei;Hu, Xin;Zhao, Jiong-Peng;Hu, Bo-Wen;Sanudo, E. Carolina;Liu, Fu-Chen;Bu, Xian-He;
[摘要]：The synthesis of an unprecedented 2-dimensional inorg. azido-Cu-hydroxyl compd. [Cu(H2O)6][{Cu2(N3)4/3(OH)(pta)}6] (H2pta = phthalic acid) was accomplished by partially substituting hydroxyl by azide. In this compd., [Cu(H2O)6]2+ not only serves as counterion to offset the high neg. charge of the 2-dimensional layers, but may also serve as template in assembly of the [Cu24] macrocyclic compd. through H-bond interactions.
