【文章名】N-Bridged diiron phthalocyanine catalyzes oxidation of benzene with H2O2 via benzene oxide with NIH shift evidenced by using 1,3,5-[D3]benzene as a probe.
N-Bridged diiron phthalocyanine catalyzes oxidation of benzene with H2O2 via benzene oxide with NIH shift evidenced by using 1,3,5-[D3]benzene as a probe.
[摘要]：Kinetic isotope effect: Incorporation of 18O from H218O2 in phenol in the presence of H216O and 16O2 and detection of benzene oxide as well as NIH shift in the oxidn. of PhH indicates that m-nitrido diiron phthalocyanine operates by a biooxidn.-like mechanism.
