Time-evolving self-organization and autonomous structural adaptation of cobalt(II) - organic framework materials with scu and pts nets.

[摘要]：The spontaneous, dynamic adjustment of equil. condition (KI/CoII ratio) is a key factor in switching the assembly direction of CoII and K4btec (btec = benzene-1,2,4,5-tetracarboxylate). {K2[Co3(btec)2(H2O)4]?H2O}n (1) with a rare scu net was generated within the first three days. A few days later a new product, {K2[Co(btec)]?H2O}n (2) with a pts net-autonomously formed.

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