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  • Intramolecular alpha-Glucosaminidation: Synthesis of Mycothiol
    [作者:AJAYI KEHINDE; THAKUR VINAY V; LAPO ROBERT C; KNAPP SPENCER,期刊:Organic Letters, 页码:2630-2633 , 文章类型: Article,,卷期:2010年12-11]
  • A protected cyclitol aglycon was tethered to an (N-arylsulfonyl)glucosamine donor by a methylene linker; the exclusively alpha-selective intramolecular glycosyation reaction was then initiated by electrophilic activation...
  • Stereoselective Additions of Thiyl Radicals to Terminal Ynamides
    [作者:BANERJEE BIPLAB; LITVINOV DMITRY N; KANG JUNGHOON; BETTALE JENNIFER D; CASTLE STEVEN L,期刊:Organic Letters, 页码:2650-2652 , 文章类型: Article,,卷期:2010年12-11]
  • Two complementary sets of conditions for radical additions of thiols to terminal ynamides are described. The use of 1 equiv of thiol affords the cis-beta-thioenamide adducts in rapid fashion (10 min) and good dr, whereas...
  • Isothiourea-Mediated Stereoselective C-Acylation of Silyl Ketene Acetals
    [作者:WOODS PHILIP A; MORRILL LOUIS C; LEBL TOMAS; SLAWIN ALEXANDRA M Z; BRAGG RYAN A; SMITH ANDREW A,期刊:Organic Letters, 页码:2660-2663 , 文章类型: Article,,卷期:2010年12-11]
  • Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides or benzoyl fluoride, giving 3-acy1-3-aryl or 3-acyl-3-alkylfuranones in excellent yields and stereoselectivities (up to...
  • Synthesis of (+/-)-Eusynstyelamide A
    [作者:BARYKINA OLGA V; SNIDER BARRY B,期刊:Organic Letters, 页码:2664-2667 , 文章类型: Article,,卷期:2010年12-11]
  • The synthesis of (+/-)-eusynstyelamide A has been accomplished in six steps in 13% overall yield from 6-bromoindole, methyl glycidate, and Boc-protected agmatine. If oxygen is carefully excluded from the reaction, the ke...
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