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Synthesis of alpha,alpha '-Linked Oligophospholes and Polyphospholes by Using Pd-Cul-Promoted Stille-Type Coupling

  作者 SAITO ARIHIRO; MATANO YOSHIHIRO; IMAHORI HIROSHI  
  选自 期刊  Organic Letters;  卷期  2010年12-11;  页码  2675-2677  
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[摘要]Palladium-copper-promoted Stille-type cross-coupling reactions between alpha-stannylphospholes and alpha-iodophospholes afforded alpha,alpha'-linked oligophospholes and polyphosphole efficiently. It has been revealed that the polyphosphole P-oxide possesses an extremely narrow band gap and a high electron-accepting ability as compared to polythiophene.

 
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