- Oligonucleotide Analogues with Integrated Bases and Backbone Part 28 Hydrazide- and Amide-Linked Analogues. 2. Di-, Tetra-, Octa-, and Decamers: Synthesis and Association
[作者:De Giacomo, F; Peifer, M; Rajic, Z; Vasella, A,期刊:Helvetica Chimica Acta, 页码:1153-1193 , 文章类型: Article,,卷期:2011年94-7]
- The protected hydrazide-linked uracil- and adenine-derived tetranucleoside analogues 17, 19, and 21 were synthesized in solution by coupling the dimeric hydrazines 6 and 10 with the carboxylic acids 7, 11, and 16. These ...
- Introduction of Adjacent Oxygen-Functionalities in Dimethyl Heptalenedicarboxylates
[作者:Rogano, F; Stojnic, D; Linden, A; Abou-Hadeed, K; Hansen, HJ,期刊:Helvetica Chimica Acta, 页码:1194-1215 , 文章类型: Article,,卷期:2011年94-7]
- The bromination of dimethyl 8-methoxy-1,6,10-trimethylheptalene-4,5-dicarboxylate (6; Scheme 2) with N-bromosuccinimide (NBS) in N,N-dimethylformamide (DMF) leads in acceptable yields to the corresponding 9-bromoheptalen...
- A Novel Synthesis of gamma,delta-Unsaturated Aldehydes from alpha-Formyl-gamma-lactones
[作者:Snowden, RL; Brauchli, R; Linder, S,期刊:Helvetica Chimica Acta, 页码:1216-1225 , 文章类型: Article,,卷期:2011年94-7]
- A preparatively useful one-step transformation of gamma,gamma-disubstituted alpha-formyl-gamma-lactones into trisubstituted gamma,delta-unsaturated aldehydes is described, by means of catalytic amounts of either AcOH or ...
- Asymmetric Total Synthesis of Stagonolide G
[作者:Ramesh, D; Rajaram, S; Prabhakar, P; Ramulu, U; Reddy, DK; Venkateswarlu, Y,期刊:Helvetica Chimica Acta, 页码:1226-1233 , 文章类型: Article,,卷期:2011年94-7]
- A simple asymmetric total synthesis of stagonolide G (1) is described. Asymmetric dihydroxylation, regioselective epoxide ring opening, and vinyl Grignard reactions are involved in generating the stereogenic centers C(4)...
- Synthesis of 2,3-Diaryl-3H-pyrrolo[2,3-c]pyridin-3-ol Derivatives by the Reaction of Aryl(3-isocyanopyridin-4-yl)methanones with Aryl Grignard Reagents
[作者:Kobayashi, K; Kozuki, T; Konishi, M; Suzuki, T; Tanmatsu, M; Konishi, H,期刊:Helvetica Chimica Acta, 页码:1234-1238 , 文章类型: Article,,卷期:2011年94-7]
- The reaction of aryl(3-isocyanopyridin-4-yl)methanones 1, easily prepared from commercially available pyridin-3-amine, with aryl Grignard reagents gave, after aqueous workup, 2,3-diaryl-3H-pyrrolo[2,3-c]pyridin-3-ols 2. ...
- Five New Biflavonoids from Daphne aurantiaca
[作者:Liang, S; Shen, YH; Tian, JM; Feng, Y; Xiong, Z; Zhang, WD,期刊:Helvetica Chimica Acta, 页码:1239-1245 , 文章类型: Article,,卷期:2011年94-7]
- Five new biflavonoids, 1-5, were isolated from the stem bark of Daphne aurantiaca. The structures were elucidated as 2,2 ''-bisteppogenin (1), 2,2 ''-bisteppogenin 7-O-beta-glucopyranoside (2), 2 ''-dehydroxy-2,2'''-bist...
- First Stereoselective Total Synthesis of Gallicynoic Acids G and H
[作者:Krishna, PR; Anitha, K,期刊:Helvetica Chimica Acta, 页码:1246-1253 , 文章类型: Article,,卷期:2011年94-7]
- A stereoselective convergent total synthesis of two acetylenic acids, gallicynoic acid G (1) and H (2), is reported, involving asymmetric reduction of alkynones 3 and 4, respectively, with the Corey-Bakshi-Sibata (CBS) c...
- Sesquiterpenoids from Fusarium sp., an Endophytic Fungus in Agriminia pilosa
[作者:Shan, WG; Chen, XX; Ying, YM; Zhan, ZJ,期刊:Helvetica Chimica Acta, 页码:1254-1259 , 文章类型: Article,,卷期:2011年94-7]
- Cultivation of the endophytic fungus isolated from the stems of Agriminia pilosa provided four new sesquiterpenoids, namely agripilols A-D (1-4, resp.). Structures of these isolates were elucidated by NMR and MS data. Th...
- Sesquiterpenoids from the Aerial Parts of Inula japonica
[作者:Gong, HQ; Wu, QX; Liu, LL; Yang, JL; Wang, R; Shi, YP,期刊:Helvetica Chimica Acta, 页码:1269-1276 , 文章类型: Article,,卷期:2011年94-7]
- Fourteen sesquiterpenoids with an eudesmane C-atom skeleton, including four new ones, (1 beta,5 alpha,7 beta,8 beta,11 beta)-5-hydroperoxy-1-hydroxyeudesm-4(15)-eno-12,8-lactone (1), (1 beta,5 beta,7 beta,8 beta)-8-(acet...
- Synthesis of 9,9-Disubstituted 9H-Pyrrolo[1,2-a]indoles by Hydriodic Acid-Catalyzed Cyclization of 1-[2-(1-Aryl(or methyl)ethenyl)phenyl]-1H-pyrroles
[作者:Kobayashi, K; Hashimoto, K; Hashimoto, H; Kondo, H; Konishi, H,期刊:Helvetica Chimica Acta, 页码:1277-1282 , 文章类型: Article,,卷期:2011年94-7]
- A novel method is reported for the synthesis of 9,9-disubstituted 9H-pyrrolo[1,2-a]indoles. Cyclization of 1-[2-(1-aryl(or methyl)ethenyl)phenyl]-1H-pyrroles, which can be easily prepared from 2-(1-aryl(or methyl)ethenyl...
- Highly Acylated 3,4-Secograyanane Diterpenoids from the Fruits of Pieris formosa
[作者:Wu, ZY; Li, HM; Li, YD; Li, HZ; Li, RT,期刊:Helvetica Chimica Acta, 页码:1283-1289 , 文章类型: Article,,卷期:2011年94-7]
- From the fruits of Pieris formosa, four new highly acylated 3,4-secograyanane diterpenoids, secorhodomollolides E-H (1-4, resp.), along with two known ones, secorhodomollolides C and D (5 and 6, resp.), were obtained. Th...
- Three New Steroidal Glycosides from the Roots of Cynanchum auriculatum
[作者:Lu, Y; Xiong, H; Teng, HL; Yang, GZ; Mei, ZN,期刊:Helvetica Chimica Acta, 页码:1296-1303 , 文章类型: Article,,卷期:2011年94-7]
- Three new C-21 steroidal glycosides with a cinnamoyl group at C(12) and a 2-methylbutanoyl group at C(20), and a straight sugar chain at C(3), namely cyanoauriculosides C-E (1-3, resp.), together with three known steroid...
- A Novel Synthesis of Isoflavones via Copper(I)-Catalyzed Intramolecular Cyclization Reaction
[作者:Li, QL; Liu, QL; Ge, ZY; Zhu, YM,期刊:Helvetica Chimica Acta, 页码:1304-1309 , 文章类型: Article,,卷期:2011年94-7]
- Isoflavone derivatives were synthesized via intramolecular cyclization of 3-(2-bromophenyl)-3-oxopropanal derivatives, using CuI as the catalyst, 2-picolinic acid (= pyridine-2-carboxylic acid) as the ligand, K2CO3 as th...
- Two New Phenolic Compounds from the Rhizomes of Gastrodia elata BLUME
[作者:Han, AR; Shin, HJ; Jeon, HR; Lee, JH; Lee, D; Seo, EK,期刊:Helvetica Chimica Acta, 页码:1310-1314 , 文章类型: Article,,卷期:2011年94-7]
- Phytochemical investigation of the rhizomes of Gastrodia elata BLUME (Orchidaceae) led to the isolation and identification of twelve compounds, including two new phenolic compounds, 4-hydroxybenzyl vanillyl ether (=4-{[(...
|