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  • Fixed or Invertible Calixarene-Based Directional Shuttles
    [作者:PIERRO TERESA; GAETA CARMINE; TALOTTA CARMEN; CASAPULLO AGOSTINO; NERI PLACIDO,期刊:Organic Letters, 页码:2650-2653 , 文章类型: Article,,卷期:2011年13-10]
  • The first examples of rotaxanes based on calixarenes threaded by dialkylammonium ions, which also represent the first examples of calixarene-based molecular shuttles, are reported. The base/acid treatment demonstrated th...
  • Regioselective Hydroformylation of Allylic Alcohols
    [作者:LIGHTBURN THOMAS E; DE PAOLIS OMAR A; CHENG KA H; TAN KIAN L,期刊:Organic Letters, 页码:2686-2689 , 文章类型: Article,,卷期:2011年13-10]
  • A highly regioselective hydroformylation of allylic alcohols is reported toward the synthesis of p-hydroxy-acid and aldehyde products. The selectivity is achieved through the use of a ligand that reversibly binds to alco...
  • Solvent Polarity Affects H Atom Abstractions from C-H Donors
    [作者:ELSHESHTAWY HAMDY S; PISCHEL UWE; NAU WERNER M,期刊:Organic Letters, 页码:2694-2697 , 文章类型: Article,,卷期:2011年13-10]
  • Kinetic solvent effects on hydrogen abstractions involving C-H donors (dienes, ethers, alkylbenzenes) have been corroborated by experiment and theory (UB3LYP/6-311++G**, polarized continuum model). To single out the effe...
  • First Total Synthesis of Rhodexin A
    [作者:JUNG MICHAEL E; YOO DONGWON,期刊:Organic Letters, 页码:2698-2701 , 文章类型: Article,,卷期:2011年13-10]
  • An efficient total synthesis of rhodexin A (1) is reported. An initial inverse-electron-demand Diels-Alder reaction of the acyldiene 6 with the silyl enol ether 7 gave the cycloadduct 8 with the required 4 contiguous ste...
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