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Free-Radical Carboalkynylation and Carboalkenylation of Olefins

  作者 LIAUTARD VIRGINIE; ROBERT FREDERIC; LANDAIS YANNICK  
  选自 期刊  Organic Letters;  卷期  2011年13-10;  页码  2658-2661  
  关联知识点  
 

[摘要]Free-radical three-component carboalkynylation and -alkenylation of olefins have been developed. These Involve the addition, across the double bond of an unactivated olefin, of a radical species alpha- to an electron-withdrawing group and an alkenyl or alkynyl moiety, derived from the corresponding sulfones.

 
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