- Synthesis and Chemistry of 2,3-Dioxabicyclo[2.2.2]octane-5,6-diols.
[作者:Valente, Peter;Avery, Thomas D.;Taylor, Dennis K.;Tiekink, Edward R. T.;,期刊:Journal of Organic Chemistry, 页码:274-282 , 文章类型: 研究论文,,卷期:2009年74-1]
- 1,4-Disubstituted 2,3-dioxabicyclo[2.2.2]oct-5-enes I (R = R1 = H, Me, Ph, R = Ph, R1 = H, etc.) were dihydroxylated with osmium tetroxide to yield diols II anti to the peroxide linkage in a highly selective manner. Redn...
- Highly Regio- and Stereoselective Cyclic Iodoetherification of 4,5-Alkadienols. An Efficient Preparation of 2-(1'(Z)-Iodoalkenyl)tetrahydrofurans.
[作者:Lu, Bo;Jiang, Xinpeng;Fu, Chunling;Ma, Shengming;,期刊:Journal of Organic Chemistry, 页码:438-441 , 文章类型: 研究论文,,卷期:2009年74-1]
- In this paper, an efficient way to synthesize 2-(1'(Z)-iodoalkenyl)tetrahydrofurans, e.g. I (R1 = n-Bu, R2 = H, R3 = H, Me; R1 = n-hexyl, R2 = H, R3 = H, n-Pr), from 4,5-alkadienols and I2 was developed. The reaction of...
- General Approach to the Total Synthesis of 9-Methoxy-Substituted Indole Alkaloids: Synthesis of Mitragynine, as well as 9-Methoxygeissoschizol and 9-Methoxy-Nb-methylgeissoschizol.
[作者:Ma, Jun;Yin, Wenyuan;Zhou, Hao;Liao, Xuebin;Cook, James M.;,期刊:Journal of Organic Chemistry, 页码:264-273 , 文章类型: 研究论文,,卷期:2009年74-1]
- Herein, the full details of the synthesis of the 9-methoxy-substituted Corynanthe indole alkaloids mitragynine, 9-methoxygeissoschizol, and 9-methoxy-Nb-methylgeissoschizol are described. Initially, an efficient synthet...
- Facile and Efficient Hypervalent Iodine(III)-Mediated meso-Functionalization of Porphyrins.
[作者:Shen, Dong-Mei;Liu, Chao;Chen, Xiao-Guang;Chen, Qing-Yun;,期刊:Journal of Organic Chemistry, 页码:206-211 , 文章类型: 研究论文,,卷期:2009年74-1]
- Highly facile and efficient synthesis of a variety of meso-functionalized porphyrins was accomplished by PhI(OAc)2-NaAuCl4 mediated direct nucleophilic substitution reactions of [5,10,15-triphenylporphyrinato]zinc(II) (Z...
- Facile Hydrolysis-Based Chemical Destruction of the Warfare Agents VX, GB, and HD by Alumina-Supported Fluoride Reagents.
[作者:Gershonov, E.;Columbus, I.;Zafrani, Y.;,期刊:Journal of Organic Chemistry, 页码:329-338 , 文章类型: 研究论文,,卷期:2009年74-1]
- A facile solvent-free hydrolysis (chem. destruction) of the warfare agents VX [O-Et S-2-(diisopropylamino)ethyl methylphosphonothioate], GB [O-iso-Pr methylphosphonofluoridate or sarin], and HD [2,2'-dichloroethyl sulfid...
- Total Synthesis of (-)-Ardeemin.
[作者:He, Bin;Song, Hao;Du, Yu;Qin, Yong;,期刊:Journal of Organic Chemistry, 页码:298-304 , 文章类型: 研究论文,,卷期:2009年74-1]
- Total synthesis of the potent anti-MDR indole alkaloid (-)-ardeemin I (R = H) and its N-acyl analogs I (R = CHO, COMe) was accomplished starting from L-tryptophan with about 2% overall yield in 20 steps. The key step de...
- Relative Basicities of ortho-, meta-, and para-Substituted Aryllithiums.
[作者:Gorecka-Kobylinska, Joanna;Schlosser, Manfred;,期刊:Journal of Organic Chemistry, 页码:222-229 , 文章类型: 研究论文,,卷期:2009年74-1]
- The relative basicities of aryllithiums bearing methoxy, chlorine, fluorine, trifluoromethyl and trifluoromethoxy substituents at the ortho, meta, and para positions have been assessed. To this end, two aryllithiums of ...
- Synthesis of 6,7,8-Trisubstituted Purines via a Copper-Catalyzed Amidation Reaction.
[作者:Ibrahim, Nada;Legraverend, Michel;,期刊:Journal of Organic Chemistry, 页码:463-465 , 文章类型: 研究论文,,卷期:2009年74-1]
- An efficient method for the synthesis of 6,7,8-trisubstituted purines, i.e. I, via a copper-catalyzed amidation reaction from easily accessible starting materials is reported. Furthermore, the resulting 6-benzylsulfanyl...
- Synthesis and Characterization of Tetrathiafulvalene-Substituted Di- and Tetraethynylethenes with p-Nitrophenyl Acceptors.
[作者:Andersson, Asbjorn S.;Kerndrup, Lasse;Madsen, Anders O.;Kilsa, Kristine;Brondsted Nielsen, Mogens;La Porta, Philip R.;Biaggio, Ivan;,期刊:Journal of Organic Chemistry, 页码:375-382 , 文章类型: 研究论文,,卷期:2009年74-1]
- Novel di- and tetraethynylethene (DEE and TEE) compds., e.g. I and II, functionalized with tetrathiafulvalene (TTF) donor groups and p-nitrophenyl acceptor groups were synthesized by palladium-catalyzed cross-coupling re...
- Syntheses and Crystal Structures of Fused Thiophenes: [7]Helicene and Double Helicene, a D2-Symmetric Dimer of 3,3'-Bis(dithieno[2,3-b:3',2'-d]thiophene).
[作者:Li, Chunli;Shi, Jianwu;Xu, Li;Wang, Yangguang;Cheng, Yanxiang;Wang, Hua;,期刊:Journal of Organic Chemistry, 页码:408-411 , 文章类型: 研究论文,,卷期:2009年74-1]
- The efficient synthesis of (TMS)2-[7]helicene (racemic I) and double helicene, a D2-sym. dimer of 3,3'-bis(dithieno[2,3-b:3',2'-d]thiophene) (racemic II) was developed. The crystal structures of I and II show both stron...
- An Efficient Synthesis of 2- and 2,6-Substituted Piperidines Using PdII-Catalyzed 1,3-Chirality Transfer Reaction.
[作者:Hande, Sudhir M.;Kawai, Nobuyuki;Uenishi, Jun'ichi;,期刊:Journal of Organic Chemistry, 页码:244-253 , 文章类型: 研究论文,,卷期:2009年74-1]
- An efficient and general method for synthesis of 2- and 2,6-substituted piperidines using PdII-catalyzed 1,3-chirality transfer reaction has been developed. The various N-protected z-amino allylic alcs. (E)-RNH(CH2)4CH:...
- Deprotonative Magnesation and Cadmation of [1,2,3]Triazolo[1,5-a]pyridines.
[作者:Bentabed-Ababsa, Ghenia;Blanco, Fernando;Derdour, Aicha;Mongin, Florence;Trecourt, Francois;Queguiner, Guy;Ballesteros, Rafael;Abarca, Belen;,期刊:Journal of Organic Chemistry, 页码:163-169 , 文章类型: 研究论文,,卷期:2009年74-1]
- regioselectively metalated at the 7 position using either Bu3MgLi or (TMP)3CdLi, the former at -10?and the latter at room temp. The lithium arylmagnesates (R = H, Me, Ph) proved to react with iodine (34-75%) or 3,4,5-tr...
- Platinum-catalyzed cycloisomerization reaction of 1,6-enyne coupling with rearrangement of propargylic esters.
[作者:Lu, Li;Liu, Xue-Yuan;Shu, Xing-Zhong;Yang, Ke;Ji, Ke-Gong;Liang, Yong-Min;,期刊:Journal of Organic Chemistry, 页码:474-477 , 文章类型: 研究论文,,卷期:2009年74-1]
- A platinum-catalyzed cycloisomerization of 1,6-enyne coupling with the rearrangement chem. of propargylic ester has been developed. Most probably, under platinum catalysis, propargylic ester undergoes the 1,3-acyloxy mi...
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