- Hyperaromatic Stabilization of Arenium Ions
[作者:KUDAVALLI JAYA S; BOYD DEREK R; COYNE DARA; KEEFFE JAMES R; LAWLOR DAVID A; MACCORMAC AOIFE C; OFERRALL RORY A MORE; RAO S NAGARAJA; SHARMA NARAIN D,期刊:Organic Letters, 页码:5550-5553 , 文章类型: Article,,卷期:2010年12-23]
- Benzene-cis- and trans-1,2-dihydrodiols undergo acid-catalyzed dehydration at remarkably different rates: k(cis)/k(trans) = 4500. This is explained by formation of a beta-hydroxycarbocation intermediate in different init...
- Rapid Biomimetic Total Synthesis of (+/-)-Rossinone B
[作者:ZHANG ZIYANG; CHEN JIAHUA; YANG ZHEN; TANG YEFENG,期刊:Organic Letters, 页码:5554-5557 , 文章类型: Article,,卷期:2010年12-23]
- A biomimetic total synthesis of (+/-)-rossinone B has been achieved through a highly efficient strategy featuring a series of rationally designed reactions, including a one-pot allylic rearrangement/oxidation reaction to...
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