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Microwave-Assisted, Pd(0)-Catalyzed Cross-Coupling of Diazirines with Aryl Halides

  作者 ZHAO XIA; WU GUOJIAO; YAN CHONG; LU KUI; LI HUI; ZHANG YAN; WANG JIANBO  
  选自 期刊  Organic Letters;  卷期  2010年12-23;  页码  5580-5583  
  关联知识点  
 

[摘要]Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed.

 
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