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  • A New Synthesis of (R)-(-)-Sumanirole (PNU-95666E)
    [作者:JEANGERARD LUDIVINE; MACE FREDERIC; DENTEL HELENE; NGO ANH NGOC; COLLET SYLVAIN; GUINGANT ANDRE; EVAIN MICHEL,期刊:SYNLETT, 页码:1473-1476 , 文章类型: Article,,卷期:2010年-10]
  • A twelve-step synthesis of (R)-(-)-sumanirole hydrochloride, starting from quinoline, has been achieved. The key reaction features selective epoxidation of the C3-C4 double bond of a 1,2-dihydroquinoline bearing a chiral...
  • Desulfonylation of Indoles and 7-Azaindoles Using Sodium tert-Butoxide
    [作者:CHAULET CHARLOTTE; CROIX CECILE; BASSET JOAN; PUJOL MARIADOLORES; VIAUDMASSUARD MARIECLAUDE,期刊:SYNLETT, 页码:1481-1484 , 文章类型: Article,,卷期:2010年-10]
  • A mild method for the desulfonylation of N-indoles and N-azaindoles is described. Deprotection is carried out under basic conditions, using sodium tert-butoxide in dioxane. Several functionalized indoles and 7-azaindoles...
  • A Short and Efficient Route from myo- to neo-Inositol
    [作者:WESSIG PABLO; MOELLNITZ KRISTIAN; HUEBNER SEBASTIAN,期刊:SYNLETT, 页码:1497-1500 , 文章类型: Article,,卷期:2010年-10]
  • An efficient route from myo- to neo-inositol is described. The key steps of the sequence are oxidation of the hydroxy group at C-5 to the corresponding ketone, followed by a highly (dr = 7.8:1) stereoselective reduction....