- Diazodiphenylmethane and monosubstituted butadienes: Kinetics and a new chapter of vinylcyclopropane chemistry
[作者:Ohta, A; Dahl, K; Raab, R; Geittner, J; Huisgen, R,期刊:Helvetica Chimica Acta, 页码:783-804 , 文章类型: Article,,卷期:2008年91-5]
- Diazodiphenylmethane (DDM) undergoes cycloadditions to 1-substituted buta-1,3-dienes exclusively at the C(3)=C(4) bond. At room temperature, the N-2 loss from the initially formed 4,5-dihydro-3H-pyrazoles 2 is faster tha...
- Biotransformation of vermitaline by Cunninghamella echinulata
[作者:Lu, YF; Chen, KY; Li, HL; Pei, YH; Liu, RH; Zhang, WD,期刊:Helvetica Chimica Acta, 页码:819-824 , 文章类型: Article,,卷期:2008年91-5]
- Biotransformation of vermitaline (1) by Cunninghamella echinulata (ACCC 30369) was carried out. Four biotransformation products were obtained and three of them were characterized as new compounds. On the basis of their N...
- Constituents from leaves of Scolopia chinensis
[作者:Lu, YN; Xie, GB; Bi, D; Shi, HM; Tu, PF,期刊:Helvetica Chimica Acta, 页码:825-830 , 文章类型: Article,,卷期:2008年91-5]
- Two new phenolic glycosides, scolochinenosides A and B (I and 2), and a new flavonoid glycoside, scoloside A (3), were isolated from the leaves of Scolopia chinensis (LOUR.) CLOS, together with eight known compounds. The...
- Yunnandaphninines F and G, new C-30 alkaloids from Daphniphyllum yunnanense
[作者:Di, YT; Liu, LL; Li, CS; Zhang, Y; Zhang, Q; Mu, SZ; Sun, QY; Yang, FM; Liu, HY; Hao, XJ,期刊:Helvetica Chimica Acta, 页码:838-843 , 文章类型: Article,,卷期:2008年91-5]
- Eight C-30 Daphniphyllum alkaloids, including two new ones, yunnandaphninines F and G (1 and 2, resp.), were isolated from the leaves and stems of Daphniphyllum yunnanense. Their structures were elucidated on the basis o...
- A one-pot synthesis of 1,2-dihydroisoquinoline derivatives from isoquinoline via a four-component reaction
[作者:Alizadeh, A; Zohreh, N,期刊:Helvetica Chimica Acta, 页码:844-849 , 文章类型: Article,,卷期:2008年91-5]
- A four-component reaction for the synthesis of 1,2-dihydroisoquinoline derivatives is described. The Huisgen 1,4-dipolar intermediate, which is produced from isoquinoline and an electron-deficient acetylene compound 1, r...
- Triterpenoids from the mangrove plant Hibiscus tiliaceus
[作者:Feng, C; Li, XM; Ji, NY; Wang, BG,期刊:Helvetica Chimica Acta, 页码:850-855 , 文章类型: Article,,卷期:2008年91-5]
- Three new triterpenoids with the rarely occurring nigrum skeleton, namely (20E)-22-hydroxynigrum-20-en-3-one (1), 21 beta-hydroxynigrum-22(29)-en-3-one (2), and 21 alpha-hydroxynigrum-22(29)-en-3-one (3), were isolated f...
- Terpenoids from two Dicranopteris species
[作者:Li, XL; Tu, L; Zhao, Y; Peng, LY; Xu, G; Cheng, X; Zhao, QS,期刊:Helvetica Chimica Acta, 页码:856-861 , 文章类型: Article,,卷期:2008年91-5]
- Two new compounds, (6S,13S)-6-{[beta-D-glucopyranosyl-(1 --> 4)-alpha-L-rhamnopyranosyl]oxy}cleroda-3,14-dien-13-ol (1) and kadsuric acid 3-methyl ester (2), together with nine known compounds, (6S,13E)6-{[ beta-D-glucop...
- Efficient iminophosphorane-mediated preparation of benzofuro-[3,2-d]pyrimidin-4(3H)-ones and unexpected ring opening products
[作者:Hu, YG; Liu, MG; Ding, MW,期刊:Helvetica Chimica Acta, 页码:862-872 , 文章类型: Article,,卷期:2008年91-5]
- The carbodiimides 4, obtained from aza-Wittig reactions of iminophosphorane 3 with aromatic isocyanates, reacted with secondary amines, phenols or alcohols in the presence of catalytic amounts of K2CO3 or sodium alkoxide...
- Six new cembranolides from the Hainan soft coral Lobophytum sp.
[作者:Chen, SH; Guo, YW; Huang, H; Cimino, G,期刊:Helvetica Chimica Acta, 页码:873-880 , 文章类型: Article,,卷期:2008年91-5]
- Six new cembrane diterpenes, lobophytolides A-F (1-6, resp.), along with six known related cembranoids, 7-12, were isolated from the Hainan soft coral Lobophytum sp. Their structures, including their relative configurati...
- Sesquiterpenoids from the resinous exudates of Commiphora opobalsamum (Burseraceae)
[作者:Shen, T; Wan, WZ; Wang, XN; Sun, LM; Yuan, HQ; Wang, XL; Ji, M; Lou, HX,期刊:Helvetica Chimica Acta, 页码:881-887 , 文章类型: Article,,卷期:2008年91-5]
- Phytochemical investigation of the exudates of Commiphora opobalsamum led to the isolation of three new sesquiterpenoids, 2 alpha-methoxy-6-oxogermacra-1(10),7(11)-dien-8,12-olide (1), 5 beta-10 alpha-hydroxy-2 alpha-met...
- Five new xanthenone O-glycosides from the roots of Polygala sibirica L.
[作者:Zhou, YH; Jiang, Y; Shi, HM; Chen, YP; Tu, PF,期刊:Helvetica Chimica Acta, 页码:897-903 , 文章类型: Article,,卷期:2008年91-5]
- Five new xanthenone O-glycosides, sibiricaxanthone C (1), sibiricaxanthone D (2), sibiricaxanthone E (3), sibiricaxanthone F (4), and sibiricaxanthone G (5) were isolated from the roots of Polygala sibirica L., together ...
- Daphnoldines A and B, two new yuzurine alkaloids with a four-ring system, from the fruits of Daphniphyllum oldhami
[作者:Zhang, Q; Di, YT; Liu, HY; Kong, NC; Gao, S; Li, CS; Zhang, Y; Li, SL; Hao, XJ,期刊:Helvetica Chimica Acta, 页码:914-919 , 文章类型: Article,,卷期:2008年91-5]
- Two new yuzurine alkaloids, daphnoldines A (1) and B (2), possessing a rare four-ring system, were isolated from the fruits of Daphniphyllum oldhami. Their structures were established on the basis of extensive spectrosco...
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