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A New Indicator for Potassium Ions at Physiological pH by Using a Macrocyclic Luminescent Metal Complex

  作者 YAN XI; LV SHASHA; GUO RONG  
  选自 期刊  Chemistry-A European Journal;  卷期  2013年19-2;  页码  464-467  
  关联知识点  
 

[摘要]Anyone for a pi-type sandwich? A luminescent indicator was developed based on the potassium-binding-induced conformational change of a macrocyclic terbium complex. The indicator adopts a random coil conformation in the absence of K+. In the presence of K+, it forms a pi-type sandwich complex with the arene, resulting in an effective energy transfer and strong luminescence (see figure).

 
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