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[摘要]：The chicken eggshell, a product of biomineralization, contains inorganic and organic substances whose content changes during the incubation process. Bloch-decay (BD) H-1, C-13, and cross-polarization (CP) C-13 nuclear magnetic resonance (NMR) spectra of chicken eggshells were acquired under magic-angle spinning (MAS). Variable contact time C-13 CP MAS NMR experiments revealed the signals of carbonyl groups from organic and inorganic compounds. In the 13C BD NMR spectra, a single peak at 168.1 ppm was detected, whereas in the H-1 BD spectra, the signals from water and the bicarbonate ion were assigned. A simultaneous decrease of the water signal in the MAS NMR spectra and an increase of the carbonate ion signal in the C-13 CP MAS NMR spectra of eggshells collected during the incubation period indicate the substitution of calcium ions by hydrogen ions in the calcium carbonate crystalline phase during the incubation of an egg. |
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