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Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure

  作者 SRIMANI DIPANKAR; FELLER MORAN; BENDAVID YEHOSHOA; MILSTEIN DAVID  
  选自 期刊  Chemical Communications;  卷期  2012年48-97;  页码  11853-11855  
  关联知识点  
 

[摘要]Imines are selectively formed by coupling of nitriles and amines under mild hydrogen pressure. The reaction is catalyzed by a bipyridine-based PNN Ru(II) pincer complex and proceeds under mild, neutral conditions at 4 bar of H-2.

 
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