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Highly efficient double-carbonylation of amines to oxamides using gold nanoparticle catalysts

  作者 MITSUDOME TAKATO; NOUJIMA AKIFUMI; MIZUGAKI TOMOO; JITSUKAWA KOICHIRO; KANEDA KIYOTOMI  
  选自 期刊  Chemical Communications;  卷期  2012年48-96;  页码  11733-11735  
  关联知识点  
 

[摘要]Hydrotalcite-supported gold nanoparticles (Au/HT) catalyzed the highly efficient double-carbonylation of amines to oxamides under mild reaction conditions. Various amines were selectively converted to the corresponding oxamides. The cooperation between gold nanoparticles and basic sites of HT plays a key role in the reaction.

 
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