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Convenient Methods to Access Chiral Camphanyl Amine Derivatives by Sodium Borohydride Reduction of D-(-)-Camphorquinone Imines

  作者 PERIASAMY MARIAPPAN; SANJEEVAKUMAR NALLURI; REDDY POLIMERA OBULA  
  选自 期刊  Synthesis;  卷期  2012年44-20;  页码  3185-3190  
  关联知识点  
 

[摘要]D-(-)-Camphorquinone imines prepared using methanolic ammonia, ethanol amine, exo-(-)-bornylamine, ethylene diamine, propylene diamine, and trans-(R, R)-1,2-diaminocyclohexane, upon reduction using sodium borohydride in methanol, give the corresponding chiral exo amino alcohol and diamine derivatives in good yields (75-95%).

 
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