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Heck Reaction of Baylis-Hillman Adducts with Iodobenzenes Using a Catalytic Amount of Pd/C under Solvent-Free Conditions

  作者 KIM HYUNSOO; LEE SANGJIN; CHOI BORAM; YOON CHEOL MIN  
  选自 期刊  Synthesis;  卷期  2012年44-20;  页码  3161-3164  
  关联知识点  
 

[摘要]The reaction of Baylis-Hillman adducts with iodobenzenes using commercially available palladium-on-carbon as a catalyst under solvent-free conditions afforded the corresponding coupling products, alpha-benzyl-beta-keto esters, in high to excellent yields. The reactions are very efficient.

 
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