Microwave-Mediated Suzuki-Miyaura Cross-Couplings of Thioether- and ortho-Substituted Methylphenylboronic Acid Esters

[摘要]：Hiterto unsuccessful cross-couplings of ortho-substituted or thioether-substituted methylphenylboronates have now been achieved, under microwave conditions, enabling the synthesis of a library of novel biaryls. Tetrakis(triphenylphosphine) palladium and various bases, for example, sodium carbonate or cesium fluoride, were found to mediate the crucial C-C bond-forming cross-coupling reaction.

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