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Rhodium(III)-Catalyzed Direct Oxidative Cross Coupling at the C5 Position of Chromones with Alkenes

  作者 SAMANTA RAJARSHI; NARAYAN RISHIKESH; ANTONCHICK ANDREY P  
  选自 期刊  Organic Letters;  卷期  2012年14-23;  页码  6108-6111  
  关联知识点  
 

[摘要]An atom-economical, Rh(III)-catalyzed, direct oxidative cross-coupling at the C5 position of chromones and flavones with a broad range of alkenes was developed. The products were formed in a highly regioselective manner in good to excellent yields. The developed method was applied in the cross-coupling of natural products for the synthesis of hybrid molecules.

 
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