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Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group

  作者 ZHAO YANCHUAN; GAO BING; NI CHUANFA; HU JINBO  
  选自 期刊  Organic Letters;  卷期  2012年14-23;  页码  6080-6083  
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[摘要]The (2-pyridyl)sulfonyl group was found to be a multifunctional group in the preparation of structurally diverse fluorinated products. It not only facilitates the copper-mediated (or catalyzed) cross-coupling reaction between a-fluoro sulfone 4a and aryl iodides, but also enables further transformations of the coupling products 2.

 
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