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Total Synthesis of the Proposed Structure of Roxbin B; the Nonidentical Outcome

  作者 YAMAGUCHI SAYURI; ASHIKAGA YOSHIKI; NISHII KENTARO; YAMADA HIDETOSHI  
  选自 期刊  Organic Letters;  卷期  2012年14-23;  页码  5928-5931  
  关联知识点  
 

[摘要]A proposed structure of roxbin B was synthesized. For the synthesis, a new synthetic method for the preparation of the hexahydroxydiphenoyl (HHDP) bridge was developed that involved the stepwise esterification of axially chiral HHDP acid anhydride. The synthesized compound was not identical to the natural roxbin B.

 
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