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Rhodium-Catalyzed [2+2] Cycloaddition of Ynamides with Nitroalkenes

  作者 SMITH DONNA L; CHIDIPUDI SURESH REDDY; GOUNDRY WILLIAM R; LAM HON WAI  
  选自 期刊  Organic Letters;  卷期  2012年14-18;  页码  4934-4937  
  关联知识点  
 

[摘要]In the presence of a diene-ligated rhodium complex, ynamides and nitroalkenes undergo catalytic [2 + 2] cycloadditions to provide cyclobutenamides. The presence of sodium tetraphenylborate was found to be crucial for the reactions to proceed efficiently.

 
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