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High-quality Fe-doped TiO2 films with superior visible-light performance

  作者 SU REN; BECHSTEIN RALF; KIBSGAARD JAKOB; VANG RONNIE T; BESENBACHER FLEMMING  
  选自 期刊  Journal of Materials Chemistry;  卷期  2012年22-45;  页码  23755-23758  
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[摘要]We report on high-quality polycrystalline Fe-doped TiO2 (Fe-TiO2) porous films synthesized via one-step electrochemical oxidation. We demonstrate that delicate properties such as the impurity concentration and the microstructure that strongly influence the performance of the material for photovoltaic and photocatalysis applications can be controlled by adjusting the electrolyte composition. Compared to Fe-doped TiO2 films prepared with traditional phosphate- or silicate-based electrolytes, our newly synthesised Fe-TiO2 films contain solely Fe dopants, which results in excellent photocatalytic and photovoltaic performance under visible light irradiation.

 
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