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Excellent long-term cycling stability of La-doped Li4Ti5O12 anode material at high current rates

  作者 BAI YUJUN; GONG CHEN; QI YONGXIN; LUN NING; FENG JUN  
  选自 期刊  Journal of Materials Chemistry;  卷期  2012年22-36;  页码  19054-19060  
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[摘要]La-doped Li4Ti5O12 (LLTO) was prepared by a simple approach using tetrabutyl titanate, LiOH center dot H2O and La(NO3)(3)(center dot)6H(2)O as raw materials, followed by sintering the dried mixture at 600 degrees C for 5 h. Without requiring any further treatments, the as-obtained LLTO could exhibit excellent long-term cycling stability, high coulombic efficiency close to 100% at various charge-discharge rates, outstanding capacity retention at high current rates of 10-50 C, remarkable performance in the temperature range from -40 to 60 degrees C, good cycling performance even subjected to overcharging to about 10 times of the reversible capacity. The La-doped LTO could be directly used as efficient anode materials for lithium-ion batteries.

 
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