Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply beta-diketiminate variants

[摘要]：Reduction of the dinuclear Co(II) nindigo complex dmp(2)Nin [Co(N{SiMe3}(2))](2), with 1 or 2 equiv. of K-0 (or KC8), affords the reduced complexes [dmp(2)Nin{Co(N{SiMe3}(2))}(2)](-) and [dmp(2)Nin-{Co(N{SiMe3}(2))}(2)](2-), respectively. Inspection of these reduced species reveals ligand-centered reduction, with each cobalt ion retaining a formal 2+ oxidation state.

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