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Sub-oxide-to-metallic, uniformly-nanoporous crystalline nanowires by plasma oxidation and electron reduction

  作者 CVELBAR UROS; CHEN ZHIQIANG; LEVCHENKO IGOR; SHEETZ R MICHAEL; JASINSKI JACEK B; MENON MADHU; SUNKARA MAHENDRA K; OSTRIKOV KOSTYA KEN  
  选自 期刊  Chemical Communications;  卷期  2012年48-90;  页码  11070-11072  
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[摘要]Sub-oxide-to-metallic highly-crystalline nanowires with uniformly distributed nanopores in the 3 nm range have been synthesized by a unique combination of the plasma oxidation, re-deposition and electron-beam reduction. Electron beam exposure-controlled oxide -> sub-oxide -> metal transition is explained using a nonequilibrium model.

 
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