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High energy resolution off-resonant spectroscopy at sub-second time resolution: (Pt(acac)(2)) decomposition

  作者 SZLACHETKO JAKUB; NACHTEGAAL MAARTEN; SA JACINTO; DOUSSE JEANCLAUDE; HOSZOWSKA JOANNA; KLEYMENOV EVGENY; JANOUSCH MARKUS; SAFONOVA OLGA V; KOENIG CHRISTIAN; VAN BOKHOVEN JEROEN A  
  选自 期刊  Chemical Communications;  卷期  2012年48-88;  页码  10898-10900  
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[摘要]We report on the decomposition of platinum acetylacetonate (Pt(acac)(2)) in hydrogen induced by flash heating. The changes in the local Pt structure were followed by high energy resolution off-resonant spectroscopy uniquely performed with sub-second time resolution. The decomposition consists of a two-step reduction process of the Pt(II) species.

 
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