Rhodium(III)-catalyzed allylic C-H bond amination. Synthesis of cyclic amines from omega-unsaturated N-sulfonylamines

[摘要]：For the first time, intramolecular allylic amination was conducted using rhodium(III) according to an "inner-sphere" type mechanism with amines activated by only one electron-withdrawing group. The activation of C(sp(3))-H bonds was chemoselective and allows the access to a variety of substituted cyclic amines such as pyrrolidines and piperidines.

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