Total Synthesis of (+)-Sch 725680: Inhibitor of Mammalian A-, B-, and Y-Family DNA Polymerases

[摘要]：The total synthesis of (+)-Sch 725680, a member of the hydrogenated azaphilone family, has been accomplished. The synthesis confirmed the absolute configuration and biological activities of the natural product. A key reaction to construct a hydrogenated azaphilone core skeleton is a Ti-mediated aldol reaction.

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