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[摘要]：A new chromogenic fluoride sensor based on 1,3-di-p-nitrophenylazocalix[4]arene-calix[4]pyrrole (1) was designed and synthesized. The color of the solution of probe 1 changed upon the addition of any F-, CH3CO2-, PhCO2-, and H2PO4- ions. However, from these ions the highly specific sensing of F- is achieved by the addition of Ca2+ which leads to a color change from light sky blue (of 1.F-) back to the original light orange color of 1. |
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