Stereochemistry of Substitution of the alpha-Dimethylamino Group by Dialkylzinc in Chiral Benzylferrocene

[摘要]：The stereochemistry of the substitution of the alpha-dimethylamino group by dimethylzinc in the presence of acetyl chloride in the chiral benzylferrocene backbone was examined. The reaction with the benzylferrocene bearing an o-bromo substituent at both ferrocene and the phenyl ring proceeded with inversion of configuration, while the reaction with the benzylferrocene bearing an o-bromo substituent at either ferrocene or the phenyl ring proceeded with retention of configuration.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内