A Mannich-Type Reaction at the meso-Methyl Position of the BODIPY Fluorophore

[摘要]：Treatment of 2,6-diethyl-4,4-difluoro-1,3,5,7,8-pentamethyl-4-bora-3a, 4a-diaza-s-indacene (BODIPY) with secondary amines in dihalomethane resulted in carbon-carbon bond formation at the meso-methyl position of BODIPY via Mannich-type reactions. The resulting modified BODIPY fluorophores possess high fluorescent quantum yields.

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