Iron(III)-Catalyzed Conia-Ene Cyclization of 2-Alkynic 1,3-Dicarbonyl Compounds

[摘要]：A cheap, simple, and effective FeCl3-catalyzed Conia-ene cyclization of 2-alkynic 1,3-dicarbonyl compounds was stereospecific to afford alkylidenecyclopentanes in (E)-isomers via the 5-exo-dig pathway. The 5-endo-dig and 6-exo-dig cyclizations were also possible, depending on the structure of the substrates.

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