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Enantioselective Rh(I)-Catalyzed Cyclization of Arylboron Compounds onto Ketones

  作者 LOW DARRYL W; PATTISON GRAHAM; WIECZYSTY MARTIN D; CHURCHILL GWYDION H; LAM HON WAI  
  选自 期刊  Organic Letters;  卷期  2012年14-10;  页码  2548-2551  
  关联知识点  
 

[摘要]Rhodium complexes based upon chiral sulfinamide-alkene, TADDOL-derived phosphoramidite, or diene ligands catalyze cyclizations of arylboron compounds ono ketones, generating a variety of products containing five-, six-, or seven-membered rings with good yields and high enantioselectivities.

 
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