Nucleophilic Addition of beta-Amino Carbanions to Arynes: One-Pot Synthesis of 4-Aryl-N-methyl-1,2,3,4-tetrahydroisoquinolines
[摘要]:A novel approach for the direct C-4 arylation of N-methyl-1,2,3,4-tetrahydroisoquinolines by nucleophilic addition of beta-aminocarbanions to benzynes is described which provides a one-pot procedure for synthesis of the title compounds.
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