Synthesis of the C1-C13 Fragment of Biselyngbyaside

[摘要]：An advanced intermediate vinyl iodide corresponding to the C1-C13 fragment of the macrolide biselyngbyaside was prepared by a cross-metathesis reaction between vinyl alcohol and alkene building blocks. The latter fragment, containing two stereocenters, was obtained by employing an asymmetric alkylation, a Wittig reaction, a hydrozirconation, and a Brown allylation as key steps.

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