Transition Metals in Organic Synthesis, Part 96. First Total Synthesis of Streptoverticillin: Unambiguous Confirmation of the Absolute Configuration

[摘要]：Using an iron-mediated construction of the carbazole framework, the first synthesis of streptoverticillin is described and the absolute configuration of the natural product is confirmed. The synthesis exploits a novel oxygen-mediated aromatization of tricarbonyliron-coordinated dihydrocarbazoles. Moreover, non-natural (R)-streptoverticillin is prepared for comparison.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内