Highly Diastereoselective and General Synthesis of Primary beta-Fluoroamines

[摘要]：A short, high yielding protocol has been developed for the highly diastereoselective (dr >20:1) and general synthesis of primary beta-fluoroamines by the enantioselective alpha-fluorination of aldehydes, conversion into the N-sulfinyl aldimlne, nucleophilic addition of various organometallic species, and 1 degrees amine liberation.

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